Dinuclear arene ruthenium thiolato complexes with fluorous side-chains
نویسندگان
چکیده
منابع مشابه
New arene ruthenium complexes with planar chirality
1,2,4-Trimethyl-cyclohexadiene reacts with RuCl3 nH2O in refluxing ethanol to afford quantitatively [RuCl2(1,2,4-C6H3Me3)] (1), the coordination of 1,2,4-trimethylbenzene to the ruthenium atom introducing planar chirality at the g-arene ligand. Th dinuclear complex 1 reacts with two equivalents of triphenylphosphine (PPh3) to give quantitatively, as a racemic mixture o enantiomers, [RuCl2(1,2,4...
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Anticancer drugs A series of monoand dinuclear (η-arene) ruthenium(II) complexes were prepared by reaction of thiosemicarbazone ligands derived from benzaldehyde and ruthenium(II) precursors of the general formula [Ru(η-arene)(μ-Cl)Cl]2, where arene=p-PrC6H4Me or C6H5C3H6COOH. These complexes were characterized by NMR and IR spectroscopy, ESI-mass spectrometry and elemental analysis. The molecu...
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New cationic diruthenium complexes of the type [(arene)(2)Ru(2)(SPh)(3)](+), arene being C(6)H(6), p-(i)PrC(6)H(4)Me, C(6)Me(6), C(6)H(5)R, where R = (CH(2))(n)OC(O)C(6)H(4)-p-O(CH(2))(6)CH(3) or (CH(2))(n)OC(O)CH=CHC(6)H(4)-p-OCH(3) and n = 2 or 4, are obtained from the reaction of the corresponding precursor [(arene)RuCl(2)](2) and thiophenol and isolated as their chloride salts. The complexe...
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A series of mononuclear ruthenium arene complexes with thiosemicarbazone (TSC) ligands (A-type, 1-8) and their corresponding di-nuclear analogues (B-type, 9-16) were synthesized and characterized by NMR, elemental analysis and HR-ESI-mass spectrometry. The molecular structures of 1, 2, 6, 9-11 and 13-16 were determined using single-crystal X-ray diffraction analysis. The Gibbs free energy of th...
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The dinuclear arene ruthenium complexes [RuCl2{C6H5(CH2)3OCO-p-C6H4-OC8H17}]2 (1) and [RuCl2{p-C6H4(CH2COOCH CH3)2}]2 (2) have been obtained by dehydrogenation of the corresponding cyclohexadiene derivative with ruthenium chloride hydrat The single-crystal X-ray structure analysis of 2 shows the arene ligands to be involved in slipped-parallel p–p stacking interactions wit neighbouring molecule...
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ژورنال
عنوان ژورنال: Inorganica Chimica Acta
سال: 2016
ISSN: 0020-1693
DOI: 10.1016/j.ica.2016.01.031